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Martins FLEE Plus IGR Trigger Spray, 82300314, Pump Spray-01/14/2016
Products in this Consumer Product Information Database (CPID) are classified based on their composition:
Substances: single chemicals
Preparations: products which contain chemicals that can be easily separated during normal use
Articles: products or product assemblies that do not contain chemicals that can be separated out from the product or assembly under normal or advertised use.
Classification: Preparation
Indicates country where product is sold.
Market: US/CanadaMartins FLEE Plus IGR Trigger Spray Insecticide is a flea and tick treatment spray-on topical flea control formula that can be applied directly to pets to provide fast-acting, long lasting, waterproof control of fleas and ticks for up to 30 days. For use on dogs, cats, puppies, and kittens eight weeks of age and older. Starts to kill existing fleas and ticks on dogs in 5 minutes. Fast-acting, long-Lasting, waterproof treatment and control of fleas and ticks. Controls flea re-infestation.
Purpose of product.
Usage: Flea and tick control for pets.Structure such as solid, liquid, aerosol etc.
Form: pump sprayDate when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
Date verified: February 15, 20245903 Genoa-Red Bluff Rd.
Pasadena TX 77507
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Chemical Composition/Ingredients
The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
Advanced
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.-
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Percent of chemical in preparation.
% Conc.Purpose served by this chemical
FunctionChemical of Concern (CoC)
Chemical of Concern(CoC)Isopropanol 000067-63-0 90.0-100.0 Solvent Yes 
CoC List
Diethylene glycol ethyl ether 000111-90-0 2.5-10.0 Solvent No Butylated hydroxyanisole (BHA) 025013-16-5 0.1-1.0 Preservative Yes CoC List
Fipronil 120068-37-3 0.29 Pesticide, Active Ingredient Yes CoC List
d-Methoprene 065733-16-6 0.28 Pesticide, Active Ingredient No -
Health Effects Information
Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Safety Data Sheet (SDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.
View Safety Data Sheet(SDS) Date that the Safety Data Sheet (SDS) was issued by manufacturer of a specific product.
SDS DATE :January 14, 2016 Health Flammability Reactivity HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product.
HMIS RATING1 3 0 Measure of Alkalinity/Acidity of substance or preparation where a level of 7 is considered as neutral.
pH Levels6.35-6.85 -
Warnings
Hazard Statements
Danger. Highly flammable liquid and vapor. Harmful if inhaled. Causes serious eye irritation. May cause drowsiness or dizziness. Suspected of causing cancer.
Precautionary Statements
General
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood.
Prevention
Keep away from heat/sparks/open flames/hot surfaces. No smoking. Keep container tightly closed. Ground/Bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wear protective gloves/protective clothing/eye protection/face protection. Wash hands thoroughly after handling. Avoid breathing mist/ vapors/spray. Use only outdoors or in a well-ventilated area.
Response
IF ON SKIN (OR HAIR): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IN CASE OF FIRE: Use foam, dry chemical, carbon dioxide to extinguish.
IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
IF EXPOSED OR CONCERNED: Get medical advice/attention.
Storage
Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up.
Disposal
Dispose of contents/container in accordance with Federal, state and local laws and regulations. -
Acute health effects
From SDS:
Hazards Identification
Danger. Highly flammable liquid and vapor. Harmful if inhaled. Causes serious eye irritation. May cause drowsiness or dizziness. Suspected of causing cancer.
Potential Health Effects
Eye Contact: Causes serious eye irritation.
Skin Contact: Not anticipated to cause skin irritation based upon component data. Not anticipated to cause skin sensitization based upon component data.
Inhalation: May cause drowsiness or dizziness. -
Chronic health effects
From SDS:
No data. -
Carcinogenicity
Fipronil Technical: The EPA has classified fipronil as a Group C – Possible Human Carcinogen based upon laboratory animal studies (increased thyroid tumors in male and female rats). Humans and rats have the same mechanism of action which produced fipronil-induced thyroid tumors in the rat; however, the rat appears to be more highly sensitive than humans. Therefore, the fipronil-induced rat thyroid tumors are not considered suggestive of a human health risk.
Butylated hydroxyanisole: IARC Group 2BButylated hydroxyanisole: NTP (Reasonably anticipated to be a human carcinogen.)Isopropanol: IARC Group 2B -
Handling information
Handle and open container in a manner as to prevent spillage. Do not eat, drink or smoke while handling this product. Immediately wash off accidental splashes of the concentrate or spray mixture from skin, clothing and out of eyes. See pesticide label for full information on product storage. Do not contaminate water, food or feed by storage of this product. Store away from sources of heat, out of direct sunlight and away from incompatible materials. Pesticides should be stored in secured areas away from children and animals.
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Disposal information
Refer to the pesticide label for full information on disposal. Pesticide wastes are toxic. Improper disposal of unused pesticide, spray mixture, or rinse water is a violation of Federal law. If these wastes cannot be used according to label instructions, contact your State Pesticide or Environmental Control Agency or the Hazardous Waste representative at the nearest EPA Regional Office for guidance in proper disposal methods. Refer to the pesticide label for full information on disposal. Do not puncture and incinerate. -
California Prop. 65 Warning
Butylated hydroxyanisole: CAS No. 025013-16-5: Carcinogen
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First Aid
Eye Contact: Hold eye open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes; then continue rinsing eye. Call a poison control center or doctor for treatment advice.Skin Contact: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15 to 20 minutes. Call a poison control center or doctor for treatment advice.Inhalation: Move person to fresh air. If person is not breathing, call 911 or an ambulance; then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice.Ingestion: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person.
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UN Global Harmonization Classification
